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We have predicted acid dissociation constants (pKa), octanol-water partition coefficients (KOW), and DPMC lipid membrane-water partition coefficients (Klipid-w) of 150 different 8-carbon containing poly-/per-fluoroalkyl carboxylic acids (C8-PFCAs) utilizing COMSO-RS theory. Different trends associated with functionalization, degree of fluorination, degree of saturation, degree of chlorination, and branching are discussed based upon the predicted values for the partition coefficients. In general, functionalization closest to the carboxylic head group had the greatest impact on the value of the predicted physicochemical properties. 

ABSTRACT We conducted a GPU-accelerated reprocessing of $$\sim 87~{{\ \rm per\ cent}}$$ of the archival data from the High Time Resolution Universe South Low Latitude (HTRU-S LowLat) pulsar survey by implementing a pulsar search pipeline that was previously used to reprocess the Parkes Multibeam Pulsar Survey (PMPS). We coherently searched the full 72-min observations of the survey with an acceleration search range up to $$|50|\, \rm m\, s^{-2}$$, which is most sensitive to binary pulsars experiencing nearly constant acceleration during 72 min of their orbital period. Here we report the discovery of 71 pulsars, including six millisecond pulsars, of which five are in binary systems, and seven pulsars with very high dispersion measures (DM $$\gt 800 \, \rm pc \, cm^{-3}$$). These pulsar discoveries largely arose by folding candidates to a much lower spectral signal-to-noise ratio than in previous surveys and by exploiting the coherence of folding over the incoherent summing of the Fourier components to discover new pulsars as well as candidate classification techniques. We show that these pulsars could be fainter and on average more distant as compared with both the previously reported 100 HTRU-S LowLat pulsars and the background pulsar population in the survey region. We have assessed the effectiveness of our search method and the overall pulsar yield of the survey. We show that through this reprocessing we have achieved the expected survey goals, including the predicted number of pulsars in the survey region, and discuss the major causes why these pulsars were missed in previous processing of the survey. 

ABSTRACT The HTRU-S Low Latitude survey data within 1° of the Galactic Centre (GC) were searched for pulsars using the Fast Folding Algorithm (FFA). Unlike traditional Fast Fourier Transform (FFT) pipelines, the FFA optimally folds the data for all possible periods over a given range, which is particularly advantageous for pulsars with low-duty cycles. For the first time, a search over acceleration was included in the FFA to improve its sensitivity to binary pulsars. The steps in dispersion measure (DM) and acceleration were optimized, resulting in a reduction of the number of trials by 86 per cent. This was achieved over a search period range from 0.6 to 432-s, i.e. 10 per cent of the observation time (4320s), with a maximum DM of 4000 pc cm−3 and an acceleration range of ±128 m s−2. The search resulted in the re-detections of four known pulsars, including a pulsar that was missed in the previous FFT processing of this survey. This result indicates that the FFA pipeline is more sensitive than the FFT pipeline used in the previous processing of the survey within our parameter range. Additionally, we discovered a 1.89-s pulsar, PSR J1746-2829, with a large DM, located 0.5 from the GC. Follow-up observations revealed that this pulsar has a relatively flat spectrum (α = −0.9 ± 0.1) and has a period derivative of ∼1.3 × 10−12 s s−1, implying a surface magnetic field of ∼5.2 × 1013 G and a characteristic age of ∼23 000 yr. While the period, spectral index, and surface magnetic field strength are similar to many radio magnetars, other characteristics such as high linear polarization are absent. 

Abstract We consider the spectrum of eigenmodes in a stellar system dominated by gravitational forces in the limit of zero collisions. We show analytically and numerically using the Lenard–Bernstein collision operator that the Landau modes, which are not true eigenmodes in a strictly collisionless system (except for the Jeans unstable mode), become part of the true eigenmode spectrum in the limit of zero collisions. Under these conditions, the continuous spectrum of true eigenmodes in a collisionless system, also known as the Case–van Kampen modes, is eliminated. Furthermore, because the background distribution function in a weakly collisional system can exhibit significant deviations from a Maxwellian distribution function over long times, we show that the spectrum of Landau modes can change drastically even in the presence of slight deviations from a Maxwellian, primarily through the appearance of weakly damped modes that may be otherwise heavily damped for a Maxwellian distribution. Our results provide important insights for developing statistical theories to describe thermal fluctuations in a stellar system, which are currently a subject of great interest forN-body simulations as well as observations of gravitational systems. 

Abstract X-ray polarization is a unique new probe of the particle acceleration in astrophysical jets made possible through the Imaging X-ray Polarimetry Explorer. Here we report on the first dense X-ray polarization monitoring campaign on the blazar Mrk 421. Our observations were accompanied by an even denser radio and optical polarization campaign. We find significant short-timescale variability in both X-ray polarization degree and angle, including an ∼90° angle rotation about the jet axis. We attribute this to random variations of the magnetic field, consistent with the presence of turbulence but also unlikely to be explained by turbulence alone. At the same time, the degree of lower-energy polarization is significantly lower and shows no more than mild variability. Our campaign provides further evidence for a scenario in which energy-stratified shock-acceleration of relativistic electrons, combined with a turbulent magnetic field, is responsible for optical to X-ray synchrotron emission in blazar jets. 

Abstract We report the Imaging X-ray Polarimetry Explorer (IXPE) polarimetric and simultaneous multiwavelength observations of the high-energy-peaked BL Lacertae object (HBL) 1ES 1959+650, performed in 2022 October and 2023 August. In 2022 October, IXPE measured an average polarization degree Π_X= 9.4% ± 1.6% and an electric-vector position angleψ_X= 53° ± 5°. The polarized X-ray emission can be decomposed into a constant component, plus a rotating component, with the rotation velocityω_EVPA= (−117 ± 12) deg day⁻¹. In 2023 August, during a period of pronounced activity of the source, IXPE measured an average Π_X= 12.4% ± 0.7% andψ_X= 20° ± 2°, with evidence (∼0.4% chance probability) for a rapidly rotating component withω_EVPA= 1864 ± 34 deg day⁻¹. These findings suggest the presence of a helical magnetic field in the jet of 1ES 1959+650 or stochastic processes governing the field in turbulent plasma. Our multiwavelength campaigns from radio to X-ray reveal variability in both polarization and flux from optical to X-rays. We interpret the results in terms of a relatively slowly varying component dominating the radio and optical emission, while rapidly variable polarized components dominate the X-ray and provide minor contribution at optical wavelengths. The radio and optical data indicate that on parsec scales the magnetic field is primarily orthogonal to the jet direction. On the contrary, X-ray measurements show a magnetic field almost aligned with the parsec jet direction. Confronting with other IXPE observations, we guess that the magnetic field of HBLs on subparsec scale should be rather unstable, often changing its direction with respect to the Very Long Baseline Array jet. 

Abstract We present multiwavelength polarization measurements of the luminous blazar Mrk 501 over a 14 month period. The 2–8 keV X-ray polarization was measured with the Imaging X-ray Polarimetry Explorer (IXPE) with six 100 ks observations spanning from 2022 March to 2023 April. Each IXPE observation was accompanied by simultaneous X-ray data from NuSTAR, Swift/XRT, and/or XMM-Newton. Complementary optical–infrared polarization measurements were also available in theB,V,R,I, andJbands, as were radio polarization measurements from 4.85 GHz to 225.5 GHz. Among the first five IXPE observations, we did not find significant variability in the X-ray polarization degree and angle with IXPE. However, the most recent sixth observation found an elevated polarization degree at >3σabove the average of the other five observations. The optical and radio measurements show no apparent correlations with the X-ray polarization properties. Throughout the six IXPE observations, the X-ray polarization degree remained higher than, or similar to, theR-band optical polarization degree, which remained higher than the radio value. This is consistent with the energy-stratified shock scenario proposed to explain the first two IXPE observations, in which the polarized X-ray, optical, and radio emission arises from different regions.